《碳材料科學與工程基礎(第2版)》內容簡介:近年來由于富勒烯和碳納米管的發現,炭材料研究受到了全球材料科學界、物理界和化學界的廣泛關注。《碳材料科學與工程基礎(第2版)》系統地介紹了炭材料的科學理論知識和工程應用實例。第一部分為緒論,介紹了寫作《碳材料科學與工程基礎(第2版)》的目的和炭材料的分類與發展史,以及炭的多樣性。第二部分為炭材料的基礎科學知識,主要介紹了炭材料的結構、性能和制備工藝,特別是炭化和石墨化的原理及其微觀結構控制技術,多孔炭的孔徑控制和炭材料摻雜其他原子的技術,炭材料的各類表征方法。第三部分主要為炭素材料的工程與應用問題,特別是新型炭材料的發展及其在能源、環保、原子能、國防方面的應用實例,涉及石墨電極,高密度各向同性石墨,高取向熱解石墨,玻璃炭,纖維狀炭,多孔炭,石墨層間化合物等。
Preface
Acknowledgments
CHAPTER 1 Introduction
1.1 Carbon materials
1.2 Short history of carbon materials
1.3 Classic carbons, new carbons, and nanocarbons
1.3.1 Classic carbons
1.3.2 New carbons
1.3.3 Nanocarbons
1.4 Construction and purposes of the present book
References
CHAPTER 2 Fundamental Science of Carbon Materials
2.1 Carbon families
2.1.1 Carbon—carbon bonds
2.1.2 Carbon families Preface
Acknowledgments
CHAPTER 1 Introduction
1.1 Carbon materials
1.2 Short history of carbon materials
1.3 Classic carbons, new carbons, and nanocarbons
1.3.1 Classic carbons
1.3.2 New carbons
1.3.3 Nanocarbons
1.4 Construction and purposes of the present book
References
CHAPTER 2 Fundamental Science of Carbon Materials
2.1 Carbon families
2.1.1 Carbon—carbon bonds
2.1.2 Carbon families
2.1.3 Structural relation to neighboring atoms
2.2 Structure and texture of carbon materials
2.2.1 Structure
2.2.2 Structure development with heat treatment(carbonization and graphitization)
2.2.3 Nanotexture
2.2.4 Microtexture (agglomeration)
2.3 Carbonization (nanotexture development)
2.3.1 Formation processes of carbon materials
2.3.2 Gas phase carbonization
2.3.3 Solid phase carbonization
2.3.4 Liquid phase carbonization
2.4 Novel techniques for carbonization
2.4.1 Template method
2.4.2 Polymer blend method
2.4.3 Electrospinning
2.4.4 Pressure carbonization
2.4.5 High—yield carbonization
2.4.6 Low—temperature carbonization
2.5 Graphitization (structure development)
2.5.1 Structure parameters
2.5.2 Graphitization behavior
2.5.3 Relations among structure parameters
2.5.4 Graphitization process
2.5.5 Graphitizing and non—graphitizing carbons
2.5.6 Heterogeneous graphitization(multiphase graphitization)
2.6 Acceleration of graphitization
2.6.1 Catalytic graphitization
2.6.2 Stress graphitization
2.6.3 Graphitization of exfoliated carbon fibers
2.7 Pore development in carbon materials
2.7.1 Pores in carbon materials
2.7.2 Identification of pores
2.7.3 Pore development in carbon materials
2.8 Introduction of foreign species
2.8.1 Possibility to introduce foreign species into carbon materials
2.8.2 Intercalation
2.8.3 Substitution
2.8.4 Doping
2.8.5 Dispersion of fine metal particles
References
CHAPTER 3 Engineering and Applications of Carbon Materials
3.1 Polycrystalline graphite blocks
3.1.1 Production
3.1.2 Applications
3.1.3 Filler cokes and binder pitches
3.1.4 Properties
3.2 Highly oriented graphite
3.2.1 Highly oriented graphite
3.2.2 Natural graphite
3.2.3 Kish graphite
3.2.4 Highly oriented pyrolytic graphite (HOPG)
3.2.5 Graphite films derived from polyimide films
3.2.6 Flexible graphite sheets
3.3 Non—graphitizing and glass—like carbons
3.3.1 Structural characteristics
3.3.2 Properties
3.3.3 Glass—like carbons
3.4 Carbon fibers
3.4.1 Classification of fibrous carbons
3.4.2 Characteristics of carbon fibers
3.4.3 PAN—based carbon fibers
3.4.4 Pitch—based carbon fibers
3.4.5 Vapor—grown carbon fibers
3.4.6 Glass—like carbon fibers
3.4.7 Carbon microcoils
3.5 Nanocarbons
3.5.1 Carbon nanotubes and nanofibers
3.5.2 Fullerenes
3.5.3 Graphene and its derivatives
3.5.4 Graphyne and graphdiyne
3.5.5 Single—wall carbon nanohorns
3.5.6 Helical carbon films
3,6 Porous carbons
3.6.1 Activated carbons
3.6.2 Novel techniques to control pore structure
3.6.3 Carbon foams (macroporous carbons)
3.7 Carbon—based composites
3.7.1 Carbon—based composites
3.7.2 Carbon/carbon composites
3.7.3 Carbon/plastics composites
3.7.4 Carbon/ceramics composites
3.7.5 Carbon/metal composites
3.8 Intercalation compounds
3.8.1 Possible applications
3.8.2 High conductivity function
3.8.3 Electrochemical functions
3.8.4 Catalytic functions
3.8.5 Gas adsorption and storage
3.8.6 Other functions
3.9 Carbon materials for energy storage
3.9.1 Rechargeable batteries
3.9.2 Electrochemical capacitors
3.9.3 Storage of hydrogen gas
3.9.4 Storage of methane gas
3.10 Carbon materials for environment remediation
3.10.1 Carbon/anatase composites
3.10.2 Carbon materials for sorption of viscous fluids
3.10.3 Carbon fibers for environment remediation
References
Index